EAN: 9783319518060

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This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis the standout result is the development of the first well-defined low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates including carbon dioxide which are as efficient as those observed in more traditional transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
Produktinformationen zuletzt aktualisiert am
01.04.2025 um 18:10 Uhr


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